How to generate Word document(doc,docx) in ASP.NET?
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You can create OpenXML documents using the Open XML SDK 2.0 for Microsoft Office. Note that this only applies to
.doc binary files from earlier versions of Word.
Documentation can be found here.
You can use WordML to create Word 2003 docx: http://www.informit.com/guides/content.aspx?g=xml&seqNum=176
I suggest getting Aspose.Words